Angry Shrimp

Name: Angry Shrimp
Ingredients: 2 tablespoons pumpkin seeds; 1/2 cup golden raisins; 2 tablespoons olive oil, divided; 3/4 cup diced white onion; 1/4 cup dried cherries, chopped; 2 teaspoons chipotle powder; 4 teaspoons chopped garlic, divided; 1/2 teaspoons ground cumin; 1/2 cup Grand Marnier orange liqueur; 20 ounces low-sodium vegetable broth; 1 tablespoon cornstarch; 2 pounds medium-large shrimp, peeled and deveined, thawed if frozen; 1 tablespoon orange zest; 6 cups kale, stems removed, chopped; 3 cups cooked brown rice